The Dietzel Group

Publications

Research papers

P. D. C. Dietzel, R. Blom, H. Fjellvåg, “Variability in the Formation and Framework Polymorphism of Metal-organic Frameworks based on Yttrium(III) and the Bifunctional Organic Linker 2,5-Dihydroxyterephthalic Acid”, Z. Anorg. Allg. Chem. 2021, 647, 15-25.

P. D. C. Dietzel, P. A. Georgiev, M. Frøseth, R. E. Johnsen, H. Fjellvåg, R. Blom, “Effect of Larger Pore Size on the Sorption Properties of Isoreticular Metal–Organic Frameworks with High Number of Open Metal Sites”, Chem. Eur. J. 2020, 26, 13523-13531, doi: 10.1002/chem.202001825.

M. H. Rosnes, B. Pato-Doldán, R. E. Johnsen, A. Mundstock, J. Caro, P. D. C. Dietzel, “Role of the metal cation in the dehydration of the microporous metal–organic frameworks CPO-27-M”, Microporous Mesoporous Mater. 2020, 309, 110503.

B. Pato-Doldán, M. H. Rosnes, D. Chernyshov, P. D. C. Dietzel, “Carbon dioxide induced structural phase transition in metal-organic frameworks CPO-27”, CrystEngComm 2020, 22, 4353-4358, doi: 10.1039/D0CE00632G. (Featured in the quarterly collection of HOT articles in the journal.)

A. Westbye, A. Aranda, P. D. C. Dietzel, L. Di Felice, “A calcium zirconate based combined material for calcium-copper chemical looping technology”, Int. J. Greenh. Gas Con. 2020, 95, 102953, doi: 10.1016/j.ijggc.2019.102953.

A. Westbye, A. Aranda, G. Grasa, P. D. C. Dietzel, I. Martínez, L. Di Felice, “Fixed Bed Reactor Validation of a Mayenite Based Combined Calcium–Copper Material for Hydrogen Production through Ca–Cu Looping”, Ind. Eng. Chem. Res. 2019, 58, 14664-14677, doi: 10.1021/acs.iecr.9b02372.

M. H. Rosnes, J. S. Mathieson, K. W. Törnroos, R. E. Johnsen, L. Cronin, P. D. C. Dietzel, “Electrospray Mass Spectrometry Investigation into the Formation of CPO-27”, Cryst. Growth Des. 2019, 19, 2089-2096, doi: 10.1021/acs.cgd.8b01657.

A. Westbye, A. Aranda, P. D. C. Dietzel, L. Di Felice, “The effect of Copper(II) oxide loading and precursor on the cyclic stability of combined mayenite based materials for calciumcopper looping technology”, Int. J. Hydrogen Energy 2019, 44, 12604-12616, doi: 10.1016/j.ijhydene.2018.11.200.

M. H. Rosnes, F. S. Nesse, M. Opitz, P. D. C. Dietzel, “Morphology control in modulated synthesis of metal-organic framework CPO-27”, Microporous Mesoporous Mater. 2019, 275, 207-213, doi: 10.1016/j.micromeso.2018.08.027.

N. Drenchev, M. H. Rosnes, P. D. C. Dietzel, A. Albinati, K. Hadjiivanov, P. A. Georgiev, “Open Metal Sites in the Metal–Organic Framework CPO-27-Cu: Detection of Regular and Defect Copper Species by CO and NO Probe Molecules”, J. Phys. Chem. C 2018, 122, 17238-17249, doi: 10.1021/acs.jpcc.8b04045.

A. A. Bezrukov, K. W. Törnroos, E. Le Roux, P. D. C. Dietzel, “Incorporation of an intact dimeric Zr₁₂ oxo cluster from a molecular precursor in a new zirconium metal-organic framework”, Chem. Commun. 2018, 54, 2735-2738, doi: 10.1039/C8CC00507A.

A. A. Bezrukov, P. D. C. Dietzel, “A Permanently Porous Yttrium-Organic Framework Based on an Extended Tridentate Phosphine Containing Linker“, Inorg. Chem. 2017, 56, 12830-12838, doi: 10.1021/acs.inorgchem.7b01574.

M. H. Rosnes, D. Sheptyakov, A. Franz, M. Frontzek, P. D. C. Dietzel, P. A. Georgiev , “On the elusive nature of oxygen binding at coordinatively unsaturated 3d transition metal centers in metal-organic frameworks”, Phys. Chem. Chem. Phys. 2017, 19, 26346-26357, doi: 10.1039/c7cp05119k.

F. Lundvall, D. S. Wragg, P. Vajeeston, P. D. C. Dietzel, H. Fjellvåg, “Ab initio structure solution and thermal stability evaluation of a new Ca(II) 3D coordination polymer using powder X-ray diffraction data”, CrystEngComm 2017, 19, 5857-5863, doi: 10.1039/c7ce01389b.

A. A. Bezrukov, K. W. Törnroos, P. D. C. Dietzel, “Modification of Network and Pore Dimensionality in Metal–Organic Frameworks Containing a Secondary Phosphine Functionality”, Cryst. Growth Des. 2017, 17, 3257-3266, doi: 10.1021/acs.cgd.7b00243.

B. Pato-Doldán, M. H. Rosnes, P. D. C. Dietzel, “An in-depth structural study of the CO₂ adsorption process in the porous metal–organic frameworks CPO-27-M”, ChemSusChem 2017, 10, 1710-1719, doi: 10.1002/cssc.201601752.

N. Drenchev, M. Mihaylov, P. D. C. Dietzel, A. Albinati, P. A. Georgiev, K. Hadjiivanov, “Low-Temperature Adsorption of H₂ and D₂ on Dehydrated and Water Precovered CPO-27-Ni”, J. Phys. Chem. C 2016, 120, 23083-23092, doi: 10.1021/acs.jpcc.6b08722.

P. D. C. Dietzel, H. Kitagawa, “Metal–Organic Frameworks – Heading towards Application”, Eur. J. Inorg. Chem. 2016, 4273-4274, doi: 10.1002/ejic.201601041.

A. A. Bezrukov, K. W. Törnroos, P. D. C. Dietzel, “Variation of desolvation behaviour in two isostructural metal-organic frameworks based on a flexible, racemic bifunctional organic linker”, Eur. J. Inorg. Chem. 2016, 4430-4439, doi: 10.1002/ejic.201600681.

F. Lundvall, D. S. Wragg, P. D. C. Dietzel, H. Fjellvag, “Two new Cu(ii) and La(iii) 2D coordination polymers, synthesis and in situ structural analysis by X-ray diffraction”, Dalton Trans. 2016, 45, 12827-12834, doi: 10.1039/C6DT02195F.

F. Lundvall, P. D. C. Dietzel, H. Fjellvag, “Crystal structure of dimethyl 4,4′-dimethoxybiphenyl-3,3′-dicarboxylate”, Acta Cryst. 2016, E72, 328-330, doi: 10.1107/S2056989016002449.

43.         F. Lundvall, P. Vajeeston, D. S. Wragg, P. D. C. Dietzel, H. Fjellvåg, “Two new series of coordination polymers and evaluation of their properties by density functional theory”, Cryst. Growth Des. 2016, 16, 339-346, doi: 10.1021/acs.cgd.5b01302.

H. Rosnes, M. Opitz, M. Frontzek, W.Lohstroh, J. P. Embs, P. A Georgiev, P. D. C. Dietzel, “Intriguing differences in hydrogen adsorption in CPO-27 materials induced by metal substitution”, J. Mater. Chem. A 2015, 3, 4827-4839, doi: 10.1039/C4TA05794E.

J. Guasch, P.D.C. Dietzel, P. Collier, N. Acerbi, “The effect of solvent and temperature in the synthesis of CPO-27-Ni by reflux”, Micropor. Mesopor. Mater. 2015, 203, 238-244, doi: 10.1016/j.micromeso.2014.10.018.

F. Lundvall, D. S. Wragg, P. D. C. Dietzel, H. Fjellvåg, “4,4′-Dimethoxybiphenyl-3,3′-dicarboxylic acid”, Acta Cryst. 2014, E70, o615, doi: 10.1107/S1600536814008599.

F. Lundvall, D. S. Wragg, P. D. C. Dietzel, H. Fjellvåg, “Dimethyl 3,3′-dimethoxybiphenyl-4,4′-di-carboxylate”, Acta Cryst. 2014, E70, o449, doi: 10.1107/S1600536814005613.

F. Lundvall, D. S. Wragg, P. D. C. Dietzel, H. Fjellvåg, “Methyl 5-iodo-2-methoxybenzoate”, Acta Cryst. 2014, E70, o462, doi: 10.1107/S1600536814005868.

C. Chmelik, A. Mundstock, P. D.C. Dietzel, J. Caro, “Idiosyncrasies of Co₂(dhtp): In situ-annealing by methanol”, Micropor. Mesopor. Mater. 2014, 183, 117-123, doi: 10.1016/j.micromeso.2013.09.002.

D. Yu, A. O. Yazaydin, J. R. Lane, P. D. C. Dietzel, R. Q. Snurr, “A Combined Experimental and Quantum Chemical Study of CO₂ Adsorption in the Metal-Organic Framework CPO-27 with Different Metals”, Chem. Sci. 2013, 4, 3544-3556, doi: 10.1039/c3sc51319j.

M. Märcz, D. S. Wragg, P. D. C. Dietzel, H. Fjellvåg, “Poly[bis(1,3-dimethylimidazolidin-2-one)([mu]2-2,5-dioxidoterephthalato)zirconium(IV)]”, Acta Cryst. 2013, E69, m152, doi:10.1107/S1600536813003449.

M. Märcz, D. S. Wragg, P. D. C. Dietzel, H. Fjellvåg, “Poly[bis(1,3-dimethyl-1,3-diazinan-2-one)(2,5-dioxidoterephthalato)zirconium(IV)]”,Acta Cryst. 2013, E69, m153, doi:10.1107/S1600536813003437.

M. Märcz, R. E. Johnsen, P. D. C. Dietzel, H. Fjellvåg, “The iron member of the CPO-27 coordination polymer series: Synthesis, characterization, and intriguing redox properties”, Micropor. Mesopor. Mater., 2012, 157, 62-74, doi: 10.1016/j.micromeso.2011.12.035.

S. Chavan, J. G. Vitillo, C. Larabi, E. A. Quadrelli, P. D. C. Dietzel, S. Bordiga, “Functionalization of CPO-27-Ni through metal hexacarbonyls: The role of open Ni²⁺ sites”, Micropor. Mesopor. Mater., 2012, 157, 56-61, doi: 10.1016/j.micromeso.2011.07.025.

C. Serre, S. Kitagawa, P. D. C. Dietzel, “Introduction to Special Issue: Metal Organic Frameworks”, Micropor. Mesopor. Mater., 2012, 157, 1-2, doi: 10.1016/j.micromeso.2012.04.044.

M. A. K. Ahmed, H. Fjellvåg, A. Kjekshus, P. D. C. Dietzel, D. S. Wragg, “The Mixed-Valence, Mixed-Ligand Complex Co₃(thd)₃(EtO)₄(tert-BuCOO)”, Z. Anorg. Allg. Chem. 2011, 637, 2175-2182, doi: 10.1002/zaac.201100253.

F. Männle, T. Rosquist Tofteberg, M. Skaugen, H. Bu, T. Peters, P. D. C. Dietzel, M. Pilz, “Polymer nanocomposite coatings based on polyhedral oligosilsesquioxanes – route for industrial manufacturing and barrier properties”, J. Nanopart. Res. 2011, 13, 4691-4701, doi: 10.1007/s11051-011-0435-7.

M. Tagliabue, C. Rizzo, R. Millini, P. D. C. Dietzel, R. Blom, S. Zanardi, “Methane storage on CPO-27-Ni pellets”, J. Porous Mater. 2011, 18, 289-296, doi: 10.1007/s10934-010-9378-0.

P. D. C. Dietzel, P. A. Georgiev, J. Eckert, R. Blom, T. Straessle, T. Unruh, “Interaction of hydrogen with accessible metal sites in metal-organic frameworks M₂(dhtp) (CPO-27-M; M=Ni, Co, Mg)”, Chem. Commun. 2010, 46, 4962-4964, doi: 10.1039/c0cc00091d.

P. D. C. Dietzel, R. Blom, H. Fjellvåg, “Coordination polymers based on the 2,5-dihydroxyterephthalate ion and alkaline earth metal (Ca, Sr) and manganese cations”, Z. Anorg. Allg. Chem. 2009, 635, 1953-1958, doi: 10.1002/zaac.200900348.

S. Chavan, F. Bonino, J. G. Vitillo, E. Groppo, C. Lamberti, P. D. C. Dietzel, A. Zecchina, S. Bordiga, “Response of CPO-27-Ni towards CO, N₂ and C₂H₄”, Phys. Chem. Chem. Phys. 2009, 11, 9811-9822, doi: 10.1039/b907258f.

P. D. C. Dietzel, V. Besikiotis, R. Blom, “Application of metal-organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide”, J. Mater. Chem. 2009, 19, 7362-7370, doi: 10.1039/b911242a.

S. Chavan, J. G. Vitillo, E. Groppo, F. Bonino, C. Lamberti, P. D. C. Dietzel, S. Bordiga, “CO Adsorption on CPO-27-Ni Coordination Polymer: Spectroscopic Features and Interaction Energy”, J. Phys. Chem. C 2009, 113, 3292-3299, doi: 10.1021/jp809872w.

P. D. C. Dietzel, R. E. Johnsen, H. Fjellvåg, S. Bordiga, E. Groppo, S. Chavan, R. Blom, “Adsorption properties and structure of CO₂ adsorbed on open coordination sites of metal–organic framework Ni₂(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction”, Chem. Commun. 2008, 5125-5127, doi: 10.1039/b810574j.

Ø. Borg, P. D.C. Dietzel, A. I. Spjelkavik, E. Z. Tveten, J. C. Walmsley, S. Diplas, S. Eri, A. Holmen, E. Rytter, “Fischer–Tropsch synthesis: Cobalt particle size and support effects on intrinsic activity and product distribution”, J. Catal. 2008, 259, 161-164, doi: 10.1016/j.jcat.2008.08.017.

P. D. C. Dietzel, R. Blom, H. Fjellvåg, “Base-induced formation of two magnesium metal-organic framework compounds with a bifunctional tetratopic ligand”, Eur. J. Inorg. Chem. 2008, 3624-3632, doi: 10.1002/ejic.200701284.

F. Bonino, S. Chavan, J. G. Vitillo, E. Groppo, G. Agostani, L. Regli, C. Lamberti, S. Bordiga, P. D. C. Dietzel, C. Prestipino, A. Zecchina, “Local structure of CPO-27-Ni coordination polymer upon dehydration and coordination of NO”, Chem. Mater. 2008, 20, 4957-4968, doi: 10.1021/cm800686k.

J. G. Vitillo, L. Regli, S. Chavan, G. Ricchiardi, G. Spoto, A. Zecchina, P. D. C. Dietzel, S. Bordiga, “Role of exposed metal sites in the hydrogen storage in MOFs”, J. Am. Chem. Soc. 2008, 130, 8386-8396, doi: 10.1021/ja8007159.

P. D. C. Dietzel, R. E. Johnsen, R. Blom, H. Fjellvåg, “Structural changes and coordinatively unsaturated metal atoms on dehydration of honeycomb analogous microporous metal-organic frameworks”, Chem. Eur. J. 2008, 14, 2389-2397, doi: 10.1002/chem.200701370.

M. A. K. Ahmed, H. Fjellvåg, A. Kjekshus, P. D. C. Dietzel, “Syntheses, structures, and polymorphism of beta-diketonato complexes – Co(thd)₃”, Z. Anorg. Allg. Chem. 2008, 634, 247-254, doi: 10.1002/zaac.200700462.

P. D. C. Dietzel, R. Dinnebier, M. Jansen, “The crystal structures of the room temperature and the low temperature phase of dimethylammonium trifluoromethanesulfonate”, Z. Anorg. Allg. Chem. 2007, 633, 1410-1416, doi: 10.1002/zaac.200700138.

M. A. K. Ahmed, H. Fjellvåg, A. Kjekshus, P. D. C. Dietzel, “Mixed Ligand Complexes of Cobalt(II) – Synthesis, Structure, and Properties of Co₄(thd)₄(OEt)₄”, Z. Anorg. Allg. Chem. 2007, 633, 1371-1381, doi: 10.1002/zaac.200700145.

J. Hafizovic, M. Bjørgen, U. Olsbye, P. D. C. Dietzel, S. Bordiga, C. Prestipino, C. Lamberti, K. P. Lillerud, “The inconsistency in adsorption properties and powder XRD data of MOF-5 is rationalized by framework interpenetration and the presence of organic and inorganic species in the nanocavities”, J. Am. Chem. Soc. 2007, 129, 3612-3620, doi: 10.1021/ja0675447.

R. H. Heyn, P. D. C. Dietzel, “The first crystal structure with pyrazine-2-carboxylato-3-amide as a ligand. Synthesis and structure of cis-N, cis-O, trans-O-diaquobis(pyrazine-2-carboxylato- 3-amide)nickel dehydrate”, J. Coord. Chem. 2007, 60, 431-437, doi: 10.1080/00958970600873562.

P. D. C. Dietzel, R. K. Kremer, M. Jansen, “Superoxide Compounds of the Large Pseudo-Alkali-Metal Ions Tetramethylammonium, -Phosphonium, and ‑Arsonium”, Chem. Asian J. 2007, 2, 66-75, doi: 10.1002/asia.200600306.

P. D. C. Dietzel, M. Jansen, “Dimeric Sandwich-like Ion Pairs in the Crystal Structure of Tetrabutylammonium Ozonide Ammoniate”, Z. Anorg. Allg. Chem. 2006, 632, 2276-2280, doi: 10.1002/zaac.200600156.

P. D. C. Dietzel, R. Blom, H. Fjellvåg, “A scandium coordination polymer constructed from trimeric octahedral building blocks and 2,5-dihydroxy­tere­phthalate”, Dalton Trans. 2006, 2055-2057, doi: 10.1039/b516365j.

P. D. C. Dietzel, B. Panella, M. Hirscher, R. Blom, H. Fjellvåg, “Hydrogen adsorp­tion in a nickel based coordination polymer with open metal sites in the cylindrical cavities of the desolvated framework”, Chem. Commun. 2006, 959‑961, doi: 10.1039/b515434k.

P. D. C. Dietzel, R. Blom, H. Fjellvåg, “Increased dimensionalities of zinc–diphenic acid coordination polymers by simultaneous or subsequent addition of neutral bridging ligands”, Dalton Trans. 2006, 586-593, doi: 10.1039/b509746k.

P. D. C. Dietzel, Y. Morita, R. Blom, H. Fjellvåg, “In situ High Temperature Single Crystal Investigations of a Dehydrated Metal-organic Framework Compound and Field-induced Magnetization of One-dimensional Metal-oxygen Chains”, Angew. Chem. 2005, 117, 6512-6516; Angew. Chem. Int. Ed. 2005, 44, 6354-6358, doi: 10.1002/anie.200501508.

P. D. C. Dietzel, M. Jansen, “Synthesis and Crystal Structures of Tris-(3,5-bis(trifluoromethyl)­phenyl)arsine oxide at 293 and 100 K and the Localization of the Trifluoromethyl Groups”, Z. Anorg. Allg. Chem. 2004, 630, 1573-1577.

P. D. C. Dietzel, R. K. Kremer, M. Jansen, “Tetraorganylammonium Superoxide Compounds: Close to Unperturbed Superoxide Ions in the Solid State”, J. Am. Chem. Soc. 2004, 126, 4689-4696, doi: 10.1021/ja039880i.

P. D. C. Dietzel, M. Jansen, “Synthesis and Crystal Structure of Tris-[3,5-bis(trifluoromethyl)phenyl]arsine”, Z. Naturforsch. 2004, 59b, 345-347, doi: 10.1002/zaac.2004004191.

P. D. C. Dietzel, M. Jansen, “Tetramethylphosphonium Hydrogen Carbonate”, Acta Crystallogr. E 2002, 58, o1003-o1004, doi: 10.1107/S1600536802013168.

P. D. C. Dietzel, M. Jansen, “Synthesis and Crystal Structure Determination of Tetra­methylammonium Auride”, Chem. Commun. 2001, 2208-2209, doi: 10.1039/b105648b.

P. D. C. Dietzel, M. Jansen, “Synthesis and Crystal Structures of Tris-(3,5-bis(trifluoromethyl)­phenyl)arsine oxide at 293 and 100 K and the Localization of the Trifluoromethyl Groups”, Z. Anorg. Allg. Chem. 2004, 630, 1573-1577.	Tris[3, 5-bis(trifluoromethyl)phenyl]arsine oxide (1) was synthesised by oxidation of tris[3, 5-bis(trifluoromethyl)phenyl]arsine with hydrogen peroxide in acetone. At 293 K, it crystallizes in the trigonal space group R3c (a = 20.2947(12) Å, c = 11.2484(13) Å, Z = 6, R1 = 0.0254). The compound undergoes a phase transition upon cooling, and it crystallizes in the monoclinic space group Cc at 100 K (a = 13.8621(13) Å, b = 18.6537(17) Å, c = 11.2874(10) Å, Z = 4, R1 = 0.0444). The crystal structures of both phases were determined. The fluorine atoms of the trifluoromethyl groups are strongly disordered at room temperature, which probably indicates a rotational motion in the plane of the fluorine atoms. This motion slows down while lowering the temperature, and the fluorine atoms are localized at 100 K. This point is illustrated by comparison of the experimental electron densities at the CF3 groups. The packing pattern in both structures consists of parallel columns of ecliptically stacked molecules. The columns are hexagonally arranged.
P. D. C. Dietzel, M. Jansen, “Synthesis and Crystal Structure of Tris-[3,5-bis(trifluoromethyl)phenyl]arsine”, Z. Naturforsch. 2004, 59b, 345-347, doi: 10.1002/zaac.2004004191.	The title compound, As[C6H3(CF3)2]3, has been synthesised by Grignard reaction from arsenic trichloride and 3,5-bis(trifluoromethyl)phenylmagnesium bromide. It crystallises in the triclinic space group P1̅ with two formula units in the asymmetric unit. The most prominent feature of the crystal structure is the protrusion of a phenyl group of one molecule into the cavity at the base of the pyramid of a second molecule. The crystal structure is then built up by densely packing these units of interlocked molecules to form columns, which are arranged in parallel in a distorted hexagonal pattern
P. D. C. Dietzel, M. Jansen, “Tetramethylphosphonium Hydrogen Carbonate”, Acta Crystallogr. E 2002, 58, o1003-o1004, doi: 10.1107/S1600536802013168.	In P(CH3)4(HCO3) the hydrogen carbonate ions form hydrogen-bonded head-to-tail dimers, as in the corresponding compounds of the heavier alkali metals.
P. D. C. Dietzel, M. Jansen, “Synthesis and Crystal Structure Determination of Tetra­methylammonium Auride”, Chem. Commun. 2001, 2208-2209, doi: 10.1039/b105648b.	Tetramethylammonium auride, the first compound of negatively charged gold with a non-metal cation, has been synthesised by cation exchange in liquid ammonia; it is isostructural to the corresponding bromide which further illustrates the similarities between the halogens and gold.

Popular science article

A. Skurtveit, K. B. Lausund, A. A. Gorzkowska-Sobas, P. D. C. Dietzel, “Metall-organiske rammeverk: Supermaterialer som kan gjøre verden til et tryggere sted”, Naturen 2020, 144, 226-233.

P. D. C. Dietzel, “Nanoporøse materialer – Hva er spesielt med nano-ingenting?”, Naturen 2012, 136, 159-173.